Porous, Crystalline, Covalent Organic Frameworks

@article{Ct2005PorousCC,
  title={Porous, Crystalline, Covalent Organic Frameworks},
  author={A. P. C{\^o}t{\'e} and Annabelle I. Benin and N. W. Ockwig and M. O'keeffe and A. Matzger and O. Yaghi},
  journal={Science},
  year={2005},
  volume={310},
  pages={1166 - 1170}
}
Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid {C6H4[B(OH)2]2} and hexahydroxytriphenylene [C18H6(OH)6]. Powder x-ray diffraction studies of the highly crystalline products (C3H2BO)6·(C9H12)1 (COF-1) and C9H4BO2 (COF-5) revealed expanded porous graphitic layers that are either staggered (COF-1, P63/mmc) or eclipsed (COF-5, P6/mmm). Their crystal structures are entirely held by strong bonds between B, C, and O… Expand
Designed Synthesis of 3D Covalent Organic Frameworks
The structure of layered covalent-organic frameworks.
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References

SHOWING 1-10 OF 24 REFERENCES
One-step synthesis and structure of an oligo(spiro-orthocarbonate).
Nanoporous Materials Science and Engineering
The topochemical 1,6-polymerization of a triene.
...
1
2
3
...