Polynuclear Lanthanide Single Molecule Magnets

@inproceedings{Tang2015PolynuclearLS,
  title={Polynuclear Lanthanide Single Molecule Magnets},
  author={Jinkui Tang and Peng Zhang},
  year={2015}
}
A Dy4 Cubane: A New Member in the Single-Molecule Toroics Family.
TLDR
The in-depth theoretical analysis on the resulting low-lying energy states, along with their variation in function of the magnetic exchange pathways, allows further light to be shed on the description of single-molecule toroics and identify the coupling scheme that better reproduces the observed data.
Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials
We survey in this chapter the lanthanide hydroxide cluster complexes since the publication of the comprehensive review on the same subject (Handbook of physics and chemistry of rare earths
A New Family of Fe4Ln4 (Ln = DyIII, GdIII, YIII) Wheel type Complexes with Ferromagnetic Interaction, Magnetocaloric Effect and Zero-field SMM Behavior
In this work, we report three isostructural Fe4Ln4 wheel type complexes with molecular formula [{Fe4(dea)4Dy4(deaH)8(µ2-OMe)4}(NO3)4]·4(H2O) (1),
Magnetic Improvement and Relaxation Mechanism of the Tb-Phthalocyanine Single-Molecule Magnet by Absorbing CH2Cl2 Molecules
The molecular characteristics, stacking structure, and magnetic properties of Tb-phthalocyanine (TbPc2) with and without the absorption of CH2Cl2 molecules were systematically investigated. The fir...
Asymmetric Dinuclear Lanthanide(III) Complexes from the Use of a Ligand Derived from 2-Acetylpyridine and Picolinoylhydrazide: Synthetic, Structural and Magnetic Studies †
TLDR
The magnetization relaxation pathways are discussed and a satisfactory fit of the temperature and field dependencies of the relaxation time τ was achieved considering a model that employs Raman, direct, and Orbach relaxation mechanisms.
Oblate versus Prolate Electron Density of Lanthanide Ions: A Design Criterion for Engineering Toroidal Moments? A Case Study on {LnIII 6 } (Ln=Tb, Dy, Ho and Er) Wheels.
TLDR
Four new complexes based on a {LnIII 6 } wheel structure are reported, three of which possess a net toroidal magnetic moment, suggesting the possibility of utilizing the popular concept of oblate and prolate electron density of the ground state MJ levels of lanthanide ions to engineer toroidal moments.
Using the Singly Deprotonated Triethanolamine to Prepare Dinuclear Lanthanide(III) Complexes: Synthesis, Structural Characterization and Magnetic Studies
The 1:1 reactions between hydrated lanthanide(III) nitrates and triethanolamine (teaH3) in MeOH, in the absence of external bases, have provided access to the dinuclear complexes [Ln2(NO3)4(teaH2)2]

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