Polymerization of Styrene Sulfonate Ethyl Ester and Styrene Sulfonate Dodecyl Ester by ATRP: Synthesis and Characterization of Polymer Brushes

@article{Lienkamp2006PolymerizationOS,
  title={Polymerization of Styrene Sulfonate Ethyl Ester and Styrene Sulfonate Dodecyl Ester by ATRP: Synthesis and Characterization of Polymer Brushes},
  author={Karen Lienkamp and Christian Ruthard and Guenter Lieser and R{\"u}diger Berger and Franziska Groehn and Gerhard Prof. Dr. Wegner},
  journal={Macromolecular Chemistry and Physics},
  year={2006},
  volume={207},
  pages={2050-2065}
}
Cylindrical polymer brushes from PSSE and PSSD have been synthesized by a 'grafting from' approach by ATRP in solution. Starting from macroinitiators with 570 and 1600 repeat units, and 10-100% reactive site density, PSSD brushes with 10-40% grafting density and PSSE brushes with 10-100% grafting density are obtained. The brushes have been characterized by 'H NMR spectroscopy, GPC-MALLS, analytical ultracentrifugation, AFM, and TEM. 
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27 Citations

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Polymerization of Styrene Sulfonate Ethyl Ester by ATRP: Synthesis and Characterization of Macromonomers for Suzuki Polycondensation
Macromonomers from SSE were synthesized via ATRP with initiators carrying functional groups that are polymerizable by Suzuki polycondensation. The material obtained had a monomodal molar mass…
Synthesis of poly(trioctylammonium p-styrenesulfonate) homopolymers and block copolymers by RAFT polymerization
Direct Synthesis of Poly(potassium 3-sulfopropyl methacrylate) Cylindrical Polymer Brushes via ATRP Using a Supramolecular Complex With Crown Ether.
TLDR
Cleavage of the side chains and further analysis reveal that the initiating efficiency of the polymerization is as low as 0.35, which solved the problem of the solubilities of the incompatible hydrophobic poly-initiator and hydrophilic ionic monomer.
Synthesis of ω-sulfonated polystyrene via reversible addition fragmentation chain transfer polymerization and postpolymerization modification
The synthesis of chain-end sulfonated polystyrene [PS (ω-sulfonated PS)] by reversible addition fragmentation chain transfer (RAFT) polymerization followed by postpolymerization modification was…
pH and salt responsive poly(N,N-dimethylaminoethyl methacrylate) cylindrical brushes and their quaternized derivatives
Synthesis of Michael Acceptor Ionomers of Poly(4-Sulfonated Styrene-co-Poly(Ethylene Glycol) Methyl Ether Acrylate).
TLDR
Well-defined copolymers of pPEGA-co-4SS were produced with molecular weights ranging from 10 kDa to 40 kDa and polydispersity indices (PDIs) of 1.06-1.18 by gel permeation chromatography against monodisperse poly(methyl methacrylate) (PMMA) standards.
Synthesis and polymerization of substituted ammonium sulfonate monomers for advanced materials applications.
TLDR
Sulfonated polymers with substituted ammonium counterions are useful polymers for obtaining unique material properties, such as organo-gelation of low polarity solvents or obtaining ionic liquidpolymers for the fabrication of solid polymer electrolytes.
Synthesis of poly(vinylidene fluoride)‐b‐poly(styrene sulfonate) block copolymers by controlled radical polymerizations
Poly(sodium styrene sulfonate)-b-poly(methyl methacrylate) diblock copolymers through direct atom transfer radical polymerization: Influence of hydrophilic–hydrophobic balance on self-organization in aqueous solution
Incorporation of poly(2‐acrylamido‐2‐methyl‐N‐propanesulfonic acid) segments into block and brush copolymers by ATRP
2-Acrylamido-2-methyl-N-propanesulfonic acid (AMPSA) was successfully polymerized via atom transfer radical polymerization (ATRP) using a copper chloride/2,2'-bipyridine (bpy) catalyst complex after…
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References

SHOWING 1-10 OF 28 REFERENCES
Polymerization of Styrene Sulfonate Ethyl Ester by ATRP: Synthesis and Characterization of Macromonomers for Suzuki Polycondensation
Macromonomers from SSE were synthesized via ATRP with initiators carrying functional groups that are polymerizable by Suzuki polycondensation. The material obtained had a monomodal molar mass…
Synthesis of Molecular Brushes with Block Copolymer Side Chains Using Atom Transfer Radical Polymerization
Brush macromolecules having poly(n-butyl acrylate-block-styrene) and poly(styrene-block-n-butyl acrylate) side chains have been synthesized by the “grafting from” approach using atom transfer radical…
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In recent years, research on cylindrical polymer brushes (or molecular bottlebrushes) has received significant attention. In this article, we discuss various strategies for their synthesis and the…
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