Polymer Percus-yevick Ideal Chain Approximation for the Lennard-jones Chain Fluid

Abstract

The structure and thermodynamic properties of the freely jointed linear chain uid with monomers interecting by the Lennard-Jones potential are studied using the polymer Percus-Yevick (PPY) ideal chain approximation. The theory is based on the Wertheim's multi-density integral-equation theory for associating uids, appropriately modiied to describe the… (More)

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