Polymer Microstructure Control in Catalytic Polymerization Exclusively by Electronic Effects of Remote Substituents

@inproceedings{Bastero2007PolymerMC,
  title={Polymer Microstructure Control in Catalytic Polymerization Exclusively by Electronic Effects of Remote Substituents},
  author={Amaia Bastero and Inigo Gçttker-Schnetmann and Caroline Rçhr and Stefan Meckinga},
  year={2007}
}
  • Amaia Bastero, Inigo Gçttker-Schnetmann, +1 author Stefan Meckinga
  • Published 2007
A series of (k-N,O)salicylaldiminato nickel methyl pyridine complexes 8a–h-pyr bearing 2,6-di-(4-R’-phenyl)phenyl groups on the imine nitrogen and varying in the remote substituents [R’= C8F17 (a), CF3 (b), F (7c), H (d), Me (e), tert.-butyl (f), OMe (g), and NMe2 (h)] were studied as precatalysts for ethylene polymerization. Complexes 8a–hpyr catalyze the… CONTINUE READING