Poly(polyoxometalate)s assembled by {Ni6PW9} units: from ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers.

Abstract

Both structure-directing effect and synergistic-directing effect of PW(9)O(34) fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni(24)-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni(40)-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.

DOI: 10.1039/c2cc34332k

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Cite this paper

@article{Huang2012PolypolyoxometalatesAB, title={Poly(polyoxometalate)s assembled by \{Ni6PW9\} units: from ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers.}, author={Ling Huang and Jie Zhang and Lin Cheng and Guo-Yu Yang}, journal={Chemical communications}, year={2012}, volume={48 77}, pages={9658-60} }