Plutonium volatility in ozonization of alkaline solutions of Pu(VI) hydroxo complexes

@article{Nikonov2011PlutoniumVI,
  title={Plutonium volatility in ozonization of alkaline solutions of Pu(VI) hydroxo complexes},
  author={Maxim V. Nikonov and Yu. M. Kiselev and Ivan G. Tananaev and Boris F. Myasoedov},
  journal={Doklady Chemistry},
  year={2011},
  volume={437},
  pages={69-71}
}
69 Processes involving the transition of chemical compounds into the gas phase are of both theoretical and practical significance. Such processes are impor� tant for actinides because their concentration, isola� tion, and purification and also isotope separation are known to present serious difficulties. Such processes are also important for plutonium. Assuming that the properties of the previously described plutonium tetroxide [1, 2] can be analogous to those of easily sub� limable osmium and… 
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The reaction of concentrated aqueous solutions of caesium or rubidium hydroxide with osmium tetraoxide, in various ratios produced the osmates(VIII), M2[OsO4(OH)2], M[OsO4(OH)], and M[O4Os(OH)OsO4](M
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The ozonising of an alkaline Pu VI solution resulted in the formation of both Pu VII and Pu VIII , and the black-blue colour earlier was ascribed to Pu VII .