Plastomeric-like polyethylenes achievable using thermally robust N,N'-nickel catalysts appended with electron withdrawing difluorobenzhydryl and nitro groups.

@article{Zhang2019PlastomericlikePA,
  title={Plastomeric-like polyethylenes achievable using thermally robust N,N'-nickel catalysts appended with electron withdrawing difluorobenzhydryl and nitro groups.},
  author={Randi Zhang and Z. Wang and Yanping Ma and G. A. Solan and Y. Sun and Wen-Hua Sun},
  journal={Dalton transactions},
  year={2019},
  volume={48 5},
  pages={
          1878-1891
        }
}
A new set of five unsymmetrical N,N'-diiminoacenaphthenes, 1-[2,6-{(4-FC6H4)2CH}2-4-NO2C6H4N]-2-(ArN)C2C10H6 (Ar = 2,6-Me2C6H3L1, 2,6-Et2C6H3L2, 2,6-iPr2C6H3L3, 2,4,6-Me3C6H2L4, 2,6-Et2-4-MeC6H2L5), have been synthesized and used to prepare their corresponding nickel(ii) halide complexes, LNiBr2 (Ni1-Ni5) and LNiCl2 (Ni6-Ni10). The molecular structures of Ni3(OH2) and Ni4 reveal distorted square pyramidal and tetrahedral geometries, respectively, while the 1H NMR spectra of all the nickel(ii… Expand
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References

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