Planar and pyramidal tetracoordinate carbon in organoboron compounds.

Abstract

Using previously proposed C(BH)2(CH)2 (16, 17) and C(CH)2B2 (22) systems with a central planar tetracoordinate carbon (ptC) atom linking two three-membered rings as building blocks, a series of stable structures containing two and three ptC centers within a molecule have been designed and computationally studied with the DFT (B3LYP/6-311+G) method… (More)

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Cite this paper

@article{Minyaev2005PlanarAP, title={Planar and pyramidal tetracoordinate carbon in organoboron compounds.}, author={Ruslan M. Minyaev and T. N. Gribanova and Vladimir I. Minkin and Andrey G. Starikov and Roald Hoffmann}, journal={The Journal of organic chemistry}, year={2005}, volume={70 17}, pages={6693-704} }