Physisorption of benzene derivatives on graphene: critical roles of steric and stereoelectronic effects of the substituent.

@article{Zhou2015PhysisorptionOB,
  title={Physisorption of benzene derivatives on graphene: critical roles of steric and stereoelectronic effects of the substituent.},
  author={Panpan Zhou and Ruiqin Q. Zhang},
  journal={Physical chemistry chemical physics : PCCP},
  year={2015},
  volume={17 18},
  pages={12185-93}
}
A series of benzene derivatives with different substituents adsorbed on graphene was investigated using a density-functional tight-binding method with a dispersion correction. Compared to benzene, the derivative with either an electron-withdrawing or -donating substituent exhibits stronger physisorption. Moreover, the steric size of the substituent is important in determining the adsorption strength, while the direction and the number of H atoms in the substituent affect the electron transfer… CONTINUE READING

From This Paper

Topics from this paper.

References

Publications referenced by this paper.
Showing 1-10 of 26 references

and J

A. Rochefor
D. Wuest, Langmuir, • 2009
View 3 Excerpts
Highly Influenced

Chem

S. Liu, C. Rong, T. Lu, J. Phys
A, • 2014

60 and V

A. Schlierf, H. Yang, +8 authors D. Beljonne
Palermo, Nanoscale, • 2013

and K

K. C. Kemp, H. Seema, +3 authors V. Chandr
S. Kim, Nanoscale, • 2013

and L

H. Zhou, F. Yu, +4 authors Y. Gu
Sun, Nanoscale, • 2013

and R

R. X. Song, S. Wangmo, +3 authors Z. G. Wan
Q. Zhang, Nanoscale, • 2013

R

A. Tkatchenko, J. DiStasio
A., R. Car and M. Scheffler, Phys. Rev. Lett., • 2012

and C

Y.-H. Zhang, K.-G. Zhou, K.-F. Xie, H.-L. Zhang, Y. Pen
5 W. Wang, Phys. Chem. Chem. Phys., • 2012

Surf

C. Thierfelder, M. Witte, S. Blankenburg, E. Rauls, W. G. Schmidt
Sci., • 2011

Eur

V. V. Ivanovskaya, A. Zobelli, +3 authors P. R. Briddon
Phys. J. B, • 2010

Similar Papers

Loading similar papers…