Photosensitized heterogeneous chemistry of ozone on organic films.

  title={Photosensitized heterogeneous chemistry of ozone on organic films.},
  author={Adla Jammoul and Saso Gligorovski and Christian George and Barbara D'Anna},
  journal={The journal of physical chemistry. A},
  volume={112 6},
The interactions of ozone with benzophenone and phenol solid films have been investigated under simulated atmospheric conditions with respect to relative humidity, pressure, temperature, and O3 concentration using a coated flow tube reactor. The steady-state reactive uptake coefficients (gammass) of ozone on benzophenone films ranged from below 10(-6) in dark conditions to approximately 4 x 10(-6) under UV-A irradiation and decreased with increasing O3 concentration in the range 28-320 ppbv. A… CONTINUE READING
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