Photophysical behavior and intramolecular energy transfer in Os(II) diimine complexes covalently linked to anthracene.


The photophysical behavior of two Os(II) complexes having a bipyridine ligand with anthracene attached directly to the bipyridine (4-(9-anthryl)-2,2'-bipyridine, bpy-AN) is reported. The two complexes [(bpy)2Os(bpy-AN)]2+ and [(bpy-AN)2Os(CO)Br]+ have (3)MLCT excited states that differ in energy by less than 800 cm(-1). Despite this fact, the observed… (More)


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