Photoisomerization and structural dynamics of two nitrosylruthenium complexes: a joint study by NMR and nonlinear IR spectroscopies.

@article{Wang2014PhotoisomerizationAS,
  title={Photoisomerization and structural dynamics of two nitrosylruthenium complexes: a joint study by NMR and nonlinear IR spectroscopies.},
  author={Jianru Wang and Fan Yang and Yan Zhao and Pengyun Yu and Xiaoyan Qiao and Jianping Wang and Hongfei Wang},
  journal={Physical chemistry chemical physics : PCCP},
  year={2014},
  volume={16 43},
  pages={24045-54}
}
In this work, the photoisomerization and structural dynamics of two isomeric nitrosylruthenium(ii) complexes [Ru(OAc)(2cqn)2NO] (H2cqn = 2-chloro-8-quinolinol) in CDCl3 and DMSO are examined using NMR and IR spectroscopic methods. The two N atoms in the 2cqn ligand are in trans position in the synthesized cis-1 isomer, while they are in cis position in the… CONTINUE READING