Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network.

@article{Jeon2017PhotoinducedRS,
  title={Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network.},
  author={Ie‐Rang Jeon and Corine Mathoni{\`e}re and Rodolphe Cl{\'e}rac and Mathieu Rouzi{\`e}res and Olivier Jeannin and Elżbieta Trzop and Eric Collet and Marc Fourmigu{\'e}},
  journal={Chemical communications},
  year={2017},
  volume={53 74},
  pages={
          10283-10286
        }
}
The organization of a molecular FeIII complex embedded in a halogen-bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework. 
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