Photoelectron circular dichroism of O 1s-photoelectrons of uniaxially oriented trifluoromethyloxirane: energy dependence and sensitivity to molecular configuration.

@article{Nalin2021PhotoelectronCD,
  title={Photoelectron circular dichroism of O 1s-photoelectrons of uniaxially oriented trifluoromethyloxirane: energy dependence and sensitivity to molecular configuration.},
  author={G. Nalin and K. Fehre and F. Trinter and N. M. Novikovskiy and N. Anders and D. Trabert and S. Grundmann and M. Kircher and Arnab Khan and Raghu Tomar and M. Hofmann and M. Waitz and I. Vela-P{\'e}rez and G. Kastirke and J. Siebert and D. Tsitsonis and H. Fukuzawa and K. Ueda and Joshua B Williams and D. Kargin and M. Maurer and C. K{\"u}stner-Wetekam and L. Marder and J. Viehmann and A. Knie and T. Jahnke and M. Ilchen and R. D{\"o}rner and R. Pietschnig and P. V. Demekhin and M. Sch{\"o}ffler},
  journal={Physical chemistry chemical physics : PCCP},
  year={2021}
}
The photoelectron circular dichroism (PECD) of the O 1s-photoelectrons of trifluoromethyloxirane (TFMOx) is studied experimentally and theoretically for different photoelectron kinetic energies. The experiments were performed employing circularly polarized synchrotron radiation and coincident electron and fragment ion detection using cold target recoil ion momentum spectroscopy. The corresponding calculations were performed by means of the single center method within the relaxed-core Hartree… Expand

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The recorded PECD experimental data and corresponding continuum multiple scattering calculations for the outermost orbitals obtained at various photon energies reveal the dramatic effect of substituting the CF3 and CH3 groups attached at the asymmetric chiral center. Expand
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