Photodissociation of TEMPO-modified peptides: new approaches to radical-directed dissociation of biomolecules.


Radical-directed dissociation of gas phase ions is emerging as a powerful and complementary alternative to traditional tandem mass spectrometric techniques for biomolecular structural analysis. Previous studies have identified that coupling of 2-[(2,2,6,6-tetramethylpiperidin-1-oxyl)methyl]benzoic acid (TEMPO-Bz) to the N-terminus of a peptide introduces a… (More)
DOI: 10.1039/c3cp54825b

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