Photocurrent-generating properties of organometallic fullerene molecules on an electrode.

@article{Matsuo2008PhotocurrentgeneratingPO,
  title={Photocurrent-generating properties of organometallic fullerene molecules on an electrode.},
  author={Yutaka Matsuo and Katsuhiko Kanaizuka and Keiko Matsuo and Yu-Wu Zhong and Takahiro Nakae and Eiichi Nakamura},
  journal={Journal of the American Chemical Society},
  year={2008},
  volume={130 15},
  pages={
          5016-7
        }
}
Compact, rigid, five-legged fullerene derivatives C60R5Me and M(C60R5)Cp (M = Fe and Ru; R = C6H4COOH, C6H4C6H4COOH, and CH2COOH) were synthesized and arrayed on an indium-tin oxide (ITO) surface. These devices exhibit a respectable quantum yield with photocurrent generation up to 18%, and, more importantly, the direction of the photocurrent can be changed not only by the molecular structure itself but also by changing the geometric configuration of the photoactive acceptor (fullerene) and… Expand
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References

Crystal structure of 5 is stored in Supporting Information
  • Nature
  • 2006