Photochemical properties of hydrofluoroethers CH3OCHF2, CH3OCF3, and CHF2OCH2CF3: reactivity toward OH, IR absorption cross sections, atmospheric lifetimes, and global warming potentials.

Abstract

Rate constants for the gas phase reactions of OH radicals with three partially fluorinated ethers, CH3OCF3 (kHFE-143a), CH3OCHF2 (kHFE-152a), and CHF2OCH2CF3 (kHFE-245fa2), were measured using a discharge flow-electron paramagnetic resonance technique over the temperature range 298-460 K. The temperature dependences of the rate constants can be represented… (More)
DOI: 10.1021/jp506377w

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Cite this paper

@article{Orkin2014PhotochemicalPO, title={Photochemical properties of hydrofluoroethers CH3OCHF2, CH3OCF3, and CHF2OCH2CF3: reactivity toward OH, IR absorption cross sections, atmospheric lifetimes, and global warming potentials.}, author={Vladimir L Orkin and Victor G Khamaganov and Andrey G Guschin}, journal={The journal of physical chemistry. A}, year={2014}, volume={118 45}, pages={10770-7} }