Photochemical Synthesis of (eta(6)-Arene)chromium Hydrido Stannyl and (eta(6)-Arene)chromium Bis(stannyl) Complexes.


Photolysis of (eta(6)-arene)Cr(CO)(3) complexes and HSnPh(3) in aromatic solvents at room temperature has led to two classes of complexes: hydrido stannyl compounds containing the eta(2)-H-SnPh(3) ligand and bis(stannyl) compounds containing two SnPh(3) ligands. The ratio between the two complexes simultaneously produced depends on the choice of the arene… (More)