Photocatalytic Reduction of CO2 with Re-Pyridyl-NHCs.

Abstract

A series of Re(I) pyridyl N-heterocyclic carbene (NHC) complexes have been synthesized and examined in the photocatalytic reduction of CO2 using a simulated solar spectrum. The catalysts were characterized through NMR, UV-vis, cyclic voltammetry under nitrogen, and cyclic voltammetry under carbon dioxide. The complexes were compared directly with a known… (More)
DOI: 10.1021/acs.inorgchem.5b02015

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