Photoactive High Explosives: Substituents Effects on Tetrazine Photochemistry and Photophysics.

@article{McGrane2016PhotoactiveHE,
  title={Photoactive High Explosives: Substituents Effects on Tetrazine Photochemistry and Photophysics.},
  author={Shawn D. McGrane and Cindy A Bolme and Margo T Greenfield and David E Chavez and Susan Kloek Hanson and Robert Jason Scharff},
  journal={The journal of physical chemistry. A},
  year={2016},
  volume={120 6},
  pages={895-902}
}
High explosives that are photoactive, i.e., can be initiated with light, offer significant advantages in reduced potential for accidental electrical initiation. We examined a series of structurally related tetrazine based photoactive high explosive materials to detail their photochemical and photophysical properties. Using photobleaching infrared absorption, we determined quantum yields of photochemistry for nanosecond pulsed excitation at 355 and 532 nm. Changes in mass spectrometry during… CONTINUE READING

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