Photoacoustic Imaging of Lithium Metal Batteries
@article{Liu2019PhotoacousticIO, title={Photoacoustic Imaging of Lithium Metal Batteries}, author={Huihui Liu and Yibo Zhao and Jiasheng Zhou and Ping Li and Shou‐Hang Bo and Sung-Liang Chen}, journal={ACS Applied Energy Materials}, year={2019} }
We demonstrate that photoacoustic microscopy (PAM) can be a potential novel imaging tool to investigate the Li metal dendrite growth, a critical issue leading to short circuit and even explosion of Li metal batteries. Our results suggest several advantages of PAM imaging of Li metal batteries: high resolution (micrometers), 3D imaging capability, deep penetration in a separator, and high contrast from bulk Li metal. Further, PAM has potential for in situ real-time imaging of Li metal batteries.
9 Citations
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References
SHOWING 1-10 OF 33 REFERENCES
Real-time 3D imaging of microstructure growth in battery cells using indirect MRI
- Materials ScienceProceedings of the National Academy of Sciences
- 2016
This work presents an alternative approach to detect a broad class of metallic dendrite growth via the dendrites’ indirect effects on the surrounding electrolyte, allowing for the application of fast 3D 1H MRI experiments with high resolution.
Dynamic Lithium Distribution upon Dendrite Growth and Shorting Revealed by Operando Neutron Imaging
- Materials ScienceACS Energy Letters
- 2019
Lithium (Li) metal has the highest theoretical capacity and is essential for energy storage technologies beyond conventional Li chemistries. However, its utilization inevitably leads to dendrite…
7Li MRI of Li batteries reveals location of microstructural lithium.
- Materials ScienceNature materials
- 2012
Techniques based on magnetic resonance imaging are demonstrated, which enable a completely non-invasive visualization and characterization of the changes that occur on battery electrodes and in the electrolyte.
Transition of lithium growth mechanisms in liquid electrolytes
- Materials Science
- 2016
Next-generation high-energy batteries will require a rechargeable lithium metal anode, but lithium dendrites tend to form during recharging, causing short-circuit risk and capacity loss, by…
Three-dimensional elemental imaging of Li-ion solid-state electrolytes using fs-laser induced breakdown spectroscopy (LIBS)
- Materials Science
- 2015
Direct chemical imaging is critical to understand and control processes that affect the performance and safety of Li-ion batteries. In this work, femtosecond-Laser Induced Breakdown Spectroscopy…
New Insights on the Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases via Cryogenic TEM.
- Materials ScienceNano letters
- 2017
Inspired by biological imaging techniques, this work demonstrates the power of cryogenic (cryo)-electron microscopy to reveal the detailed structure of EDLi and the SEI composition at the nanoscale while minimizing beam damage during imaging.
Li Distribution Heterogeneity in Solid Electrolyte Li10GeP2S12 upon Electrochemical Cycling Probed by 7Li MRI.
- Materials ScienceThe journal of physical chemistry letters
- 2018
MRI is demonstrated a powerful tool for noninvasively monitoring the Li distribution at the interfaces and in the bulk of all-solid-state batteries as well as a convenient strategy for improving interfacial stability.
Dual-view photoacoustic microscopy for quantitative cell nuclear imaging.
- PhysicsOptics letters
- 2018
Dual-view OR-PAM is introduced to improve axial resolution, achieving three-dimensional (3D) resolution isotropy, and revealing the 3D structure of cell nuclei in detail, which facilitates quantitative cell nuclear analysis.
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
- Materials ScienceScience
- 2017
Cryo–electron microscopy can preserve reactive metals and thus reveal the atomic structure of a lithium metal dendrite and atomically resolve individual lithium metal atoms and their interface with the solid electrolyte interphase (SEI).
In Situ Neutron Depth Profiling of Lithium Metal-Garnet Interfaces for Solid State Batteries.
- Materials ScienceJournal of the American Chemical Society
- 2017
The garnet-based solid state electrolyte (SSE) is considered a promising candidate to realize all solid state lithium (Li) metal batteries. However, critical issues require additional investigation…