Phosphine catalyzed aldol reaction between ketene silyl acetals and aldehydes: nucleophilic O–Si and C–Si bond cleavage by phosphines

@inproceedings{Matsukawa2000PhosphineCA,
  title={Phosphine catalyzed aldol reaction between ketene silyl acetals and aldehydes: nucleophilic O–Si and C–Si bond cleavage by phosphines},
  author={Satoru Matsukawa and Naoko Okano and Tsuneo Imamoto},
  year={2000}
}
Abstract A highly nucleophilic phosphine, tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP), catalyzes the aldol reaction between ketene silyl acetals and aldehydes to give the corresponding aldol products in good to high yields. This reaction is considered to proceed through naked enolates produced by nucleophilic O–Si and C–Si bond cleavage. 

Create an AI-powered research feed to stay up to date with new papers like this posted to ArXiv

Citations

Publications citing this paper.