Phenylglycine methyl ester, a useful tool for absolute configuration determination of various chiral carboxylic acids

@article{Yabuuchi2000PhenylglycineME,
  title={Phenylglycine methyl ester, a useful tool for absolute configuration determination of various chiral carboxylic acids},
  author={Yabuuchi and Takenori Kusumi},
  journal={The Journal of organic chemistry},
  year={2000},
  volume={65 2},
  pages={
          397-404
        }
}
A new chiral anisotropic reagent, phenylglycine methyl ester (PGME), developed for the elucidation of the absolute configuration of chiral alpha,alpha-disubstituted acetic acids, has turned out to be applicable to other substituted carboxylic acids, such as chiral alpha-hydroxy-, alpha-alkoxy-, and alpha-acyloxy-alpha, alpha-disubstituted acetic acids, as well as to chiral beta, beta-disubstituted propionic acids. Because a carboxylic moiety is convertible from other functional groups, e.g… CONTINUE READING
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