Phenanthroline‐ and Terpyridine‐Substituted Tetralactam Macrocycles: A Facile Route to Rigid Di‐ and Trivalent Receptors and Interlocked Molecules

@article{Dzyuba2012PhenanthrolineAT,
  title={Phenanthroline‐ and Terpyridine‐Substituted Tetralactam Macrocycles: A Facile Route to Rigid Di‐ and Trivalent Receptors and Interlocked Molecules},
  author={Egor V. Dzyuba and Bilge Baytekin and Dominik Sattler and Christoph A. Schalley},
  journal={European Journal of Organic Chemistry},
  year={2012},
  volume={2012},
  pages={1171-1178}
}
Bromo-substituted Hunter/Vogtle-type tetralactam macrocycles (TLMs) represent key intermediates for the attachment of terpyridyl and phenanthroline metal binding sites through cross-coupling reactions. From these monovalent precursors, metal complexes can easily be obtained that present the macrocycles in a multivalent fashion. Depending on the nature of the metal ion, the properties of the complexes can be tuned with respect to valency (e.g., phen-TLM + CuI: divalent, phen-TLM + FeII… Expand
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