Phasenbildungen von Lysolezithin bei Gefrierätzung

Abstract

s t r e t ch a t 2020 cm -1. Our earlier ana ly t i ca l d a t a sugges ted t he fo rmula (Ph@)~RhH, b u t more deta i led s tudies now indica te t h a t our c o m p o u n d too ha s t he fo rmula (PhaP)aRhH and we appea r to h a v e isolated (PhaP)aRhH in a di f ferent form. I t reac t s readi ly wi th P hsP to yield (Ph~P)41RhH as does K e i m ' s c o m p o u n d also. Deta i l s of these s tud ies will be pub l i shed shor t ly , b u t we seek to correct here t he earlier sugges t ion t h a t t he complex was t he bis-triphosphine complex. The reac t ions of (PhaP)aRhH wi th PhaP and t he new reac t ions repor ted for it and for ( P h a P ) , R h H are in no w a y affected b y these fu r t he r s tudies . Inc identa l ly , t he s t r uc tu r e of ( P h a P ) 4 R h H . 1 C6H~ h a s now been repor ted by Baker and Pau l i ng [3]The four p h o s p h o r u s a t o m s fo rm a regular t e t r a h e d r o n a b o u t t he Rh(I) a tom.

DOI: 10.1007/BF01185749

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Cite this paper

@article{Ruska2005PhasenbildungenVL, title={Phasenbildungen von Lysolezithin bei Gefrier{\"a}tzung}, author={Carla Ruska}, journal={Naturwissenschaften}, year={2005}, volume={56}, pages={637-638} }