Permittivity-dependent entropy driven complexation ability of cone and paco tetranitro-calix[4]arene toward para-substituted phenols.

Abstract

Considering the importance of the polarizability of the rings of calixarenes in the entropy-driven interaction processes, we examined the effect of entropy compensation on the complex formation of cone and partial cone (paco) conformers of tetranitro-calix [4]arene, possessing O-ethyl substituents at the lower rim. Both calixarene conformers were fully… (More)
DOI: 10.1021/jp803498v

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@article{KunsgiMt2008PermittivitydependentED, title={Permittivity-dependent entropy driven complexation ability of cone and paco tetranitro-calix[4]arene toward para-substituted phenols.}, author={S{\'a}ndor Kuns{\'a}gi-M{\'a}t{\'e} and Zsolt Cs{\'o}k and Angela Tuzi and L{\'a}szl{\'o} E. Koll{\'a}r}, journal={The journal of physical chemistry. B}, year={2008}, volume={112 37}, pages={11743-9} }