Pentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation
@article{Konkena2016PentlanditeRA, title={Pentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation}, author={Bharathi Konkena and Kai Junge Puring and I. Sinev and Stefan M Piontek and Oleksiy Khavryuchenko and Johannes P. D{\"u}rholt and Rochus Schmid and H. T{\"u}ys{\"u}z and M. Muhler and W. Schuhmann and Ulf-Peter Apfel}, journal={Nature Communications}, year={2016}, volume={7} }
The need for sustainable catalysts for an efficient hydrogen evolution reaction is of significant interest for modern society. Inspired by comparable structural properties of [FeNi]-hydrogenase, here we present the natural ore pentlandite (Fe4.5Ni4.5S8) as a direct ‘rock' electrode material for hydrogen evolution under acidic conditions with an overpotential of 280 mV at 10 mA cm−2. Furthermore, it reaches a value as low as 190 mV after 96 h of electrolysis due to surface sulfur depletion… CONTINUE READING
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