Pentadentate thioether-oxime macrocyclic and quasi-macrocyclic complexes of copper(II) and nickel(II)

@article{Prushan2000PentadentateTM,
  title={Pentadentate thioether-oxime macrocyclic and quasi-macrocyclic complexes of copper(II) and nickel(II)},
  author={Michael J. Prushan and A. Addison and R. Butcher},
  journal={Inorganica Chimica Acta},
  year={2000},
  volume={300},
  pages={992-1003}
}
  • Michael J. Prushan, A. Addison, R. Butcher
  • Published 2000
  • Chemistry
  • Inorganica Chimica Acta
  • Abstract A series of new pentadentate thioether-oximes (TtoxH2, MeTtoxH2, OdtoxH2) were synthesized along with their Ni(II) and Cu(II) complexes. BF2 +-bridging is accomplished by reaction of the H-bonded oxime complex with BF3·OEt2, though when Cu(BF4)2 is used as the Cu(II) salt, direct macrocyclization occurs during the metal complexation reaction. Crystallographic studies reveal: [Cu(TtoxH)]ClO4 has a N2S3 square-pyramidal geometry, with an H-bond forming a quasi-macrocycle. In [Cu(OdtoxH… CONTINUE READING
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