Pentadentate thioether-oxime macrocyclic and quasi-macrocyclic complexes of copper(II) and nickel(II)

@article{Prushan2000PentadentateTM,
  title={Pentadentate thioether-oxime macrocyclic and quasi-macrocyclic complexes of copper(II) and nickel(II)},
  author={Michael J. Prushan and A. Addison and R. Butcher},
  journal={Inorganica Chimica Acta},
  year={2000},
  volume={300},
  pages={992-1003}
}
  • Michael J. Prushan, A. Addison, R. Butcher
  • Published 2000
  • Chemistry
  • Inorganica Chimica Acta
    • Abstract A series of new pentadentate thioether-oximes (TtoxH2, MeTtoxH2, OdtoxH2) were synthesized along with their Ni(II) and Cu(II) complexes. BF2 +-bridging is accomplished by reaction of the H-bonded oxime complex with BF3·OEt2, though when Cu(BF4)2 is used as the Cu(II) salt, direct macrocyclization occurs during the metal complexation reaction. Crystallographic studies reveal: [Cu(TtoxH)]ClO4 has a N2S3 square-pyramidal geometry, with an H-bond forming a quasi-macrocycle. In [Cu(OdtoxH… CONTINUE READING
    View via Publisher
    lasalle.edu
    41 Citations
    Background Citations
    2

    Figures and Tables from this paper

    Figures and Tables

    41 Citations
    Citation Type

    Citation Type

    Copper(II) complexes of tetradentate thioether-oxime ligands
    • 24
    • PDF
    A new unsymmetrical vic-dioxime bearing salicylaldehyde 4-aminobenzoylhydrazone and its homo-and heterotrinuclear complexes with copper(II) and nickel(II) ions
    • 11
    The copper(I)/copper(II) transition in complexes with 8-alkylthioquinoline based multidentate ligands
    • 30
    Structural and magnetic properties of polynuclear oximate copper complexes with different topologies
    • 2
    Synthesis, characterization and properties of tetra((1-hydroxyimino-methylnaphthalen-2-yloxy)methyl)ethene and its homo-dinuclear metal complexes: a combined experimental and theoretical investigation.
    • 12
    Five-coordinate dicarboxylate complexes of copper (+2) and zinc (+2)
    • 7
    Alcohol-soluble functional vic-dioxime bearing alcoholhexylsulfanyl moieties: preparation, spectroscopy and electrochemistry
    • 13
    Synthesis, characterization and structure of nickel(II) complexes of a 16-membered mixed-donor macrocyclic Schiff base ligand, potentially hexadentate, bearing two pendant alcohol functions
    • 31
    Synthesis, characterization and electrochemical investigation of a novel vic-dioxime ligand and its some transition metal complexes
    • 12
    Fluorescent vic-dioxime-type ligand and its mono- and dinuclear complexes: The preparation, spectroscopy, and electrochemistry of its various complexes
    • 20
    • PDF

    References

    SHOWING 1-10 OF 121 REFERENCES
    Mono- and Trinuclear Nickel(II) Complexes with Sulfur-Containing Oxime Ligands: Uncommon Templated Coupling of Oxime with Nitrile.
    • 49
    • PDF
    Synthesis and crystal structure of a copper(II) complex with a tetradentate dithiadioxime ligand
    • 6
    Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(II) perchlorate
    • 5,835
    The 1, 8-bis(2′-pyridyl)-3, 6-dithiaoctane complex of nickel(II): X-ray crystal structure and borohydride adduct formation
    • 15
    Crown thioether chemistry: homoleptic hexakis(thioether) complexes of nickel(II)
    • 50
    Nickel(II) complexes with dithiadiiminoamine and dithiabis(thiosemicarbazone) ligands
    • 41
    Thioether-Coordinated Nickel Oxidation States. A Ni(III)S(2)N(4) Family Incorporating Hexadentate Thioether-Azo-Oxime Chelation.
    • 20
    Metal-Ligand Bonding in Coinage Metal-Phosphine Complexes: The Synthesis and Structure of Some Low-Coordinate Silver(I)-Phosphine Complexes.
    • 42
    Synthesis, structure, and reactivity of the nickel(II) complex of 7-aza-1,4-dithiacyclononane
    • 39
    COPPER(II) AND NICKEL(II) COMPLEXES OF DIANIONIC AND TETRAANIONIC DINUCLEATING MACROCYCLES
    • 73