Pd-Catalyzed Transfer of Difluorocarbene.


The study of transition-metal difluorocarbene complex has long been a subject of active investigation, but the transition-metal-catalyzed transfer of difluorocarbene remains a significant challenge. The Pd-catalyzed transfer of difluorocarbene is described to realize the coupling reaction of boronic acids with difluorocarbene to give (difluoromethyl)arenes… (More)
DOI: 10.1021/acs.orglett.6b02141


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