Pd – K carbene complexes via one-electron reductions of palladium radical carbenes †

Abstract

Heterobimetallic Pd–K carbenes featuring Pd–Ccarbene–K moieties were synthesized via an unprecedented sequential substitution/reduction reaction from a radical precursor, [{PCc(sp)P}PdI] ([PC(sp)P] 1⁄4 bis[2-(di-iso-propylphosphino)-4-tert-butylphenyl]methylene). Polymeric structures were observed in the solid state for the heterobimetallic compounds that… (More)

5 Figures and Tables

Topics

  • Presentations referencing similar topics