Pd(II)-catalyzed C(sp2)-H hydroxylation with R2(O)P-coordinating group.


A novel R2(O)P-directed Pd(II)-catalyzed C-H hydroxylation to synthesize various substituted 2'-phosphorylbiphenyl-2-ol compounds is described. Notably, the reaction operates under mild conditions and shows good functional group tolerance, high selectivity, and yield. 
DOI: 10.1021/ol403028a


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