Pd(II) and Ni(II) complexes featuring a "phosphasalen" ligand: synthesis and DFT study.


A phosphorus analog of salen ligands featuring iminophosphorane functionalities in place of the imine groups was synthesised in 2 steps from o-diphenylphosphinophenol via the preparation of the corresponding bis-aminophosphonium salt. This novel tetradentate ligand (1), which we named phosphasalen, was coordinated to Pd(II) and Ni(II) metal centres… (More)
DOI: 10.1039/c1dt10906e


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