Parent, Unsubstituted Hemiporphycene: Synthesis and Properties.

Abstract

Among seven possible nitrogen-in constitutional isomers of porphyrin only one, porphycene, has been obtained so far in the free, unsubstituted form. Herein, the synthesis of another isomer, parent hemiporphycene (HPc), and its thorough structural, spectral, photophysical, electrochemical, and theoretical characterization are reported. Most of the properties… (More)
DOI: 10.1002/chem.201603560

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