Palladium complexes with a tridentate PNO ligand. Synthesis of eta1-allyl complexes and cross-coupling reactions promoted by boron compounds.

@article{Crociani2010PalladiumCW,
  title={Palladium complexes with a tridentate PNO ligand. Synthesis of eta1-allyl complexes and cross-coupling reactions promoted by boron compounds.},
  author={Bruno Crociani and Simonetta Antonaroli and Marcello Burattini and Paola Paoli and Patrizia Rossi},
  journal={Dalton transactions},
  year={2010},
  volume={39 15},
  pages={3665-72}
}
The iminophosphine 2-(2-Ph(2)P)C(6)H(4)N=CHC(6)H(4)OH (P-N-OH) reacts with [Pd(mu-Cl)(eta(3)-C(3)H(5))](2) yielding [PdCl(P-N-O)] and propene. In the presence of NEt(3), the reaction of P-N-OH with [Pd(mu-Cl)(eta(3)-1-R(1),3-R(2)C(3)H(3))](2) (R(1) = R(2) = H, Ph; R(1) = H, R(2) = Ph) affords the eta(1)-allyl derivatives [Pd(eta(1)-1-R(1),3-R(2)C(3)H(3))](P… CONTINUE READING