Palladium-catalyzed oxidative arylating carbocyclization of allenynes.

Abstract

Vinylallenes or cross-conjugated trienes are obtained selectively in the title reaction. Two possible mechanisms are suggested to rationalize the formation of the different types of products. Control experiments indicate that p-benzoquinone (BQ) plays an important role as a ligand in addition to its role as an oxidant. E=CO(2)Me.

DOI: 10.1002/anie.201107592