Palladium-catalyzed carbohalogenation: bromide to iodide exchange and domino processes.

Abstract

Aryl bromides have been used to prepare a variety of nitrogen- and oxygen-containing heterocycles featuring new carbon-carbon and carbon-iodine bonds. This palladium-catalyzed carbohalogenation requires potassium iodide for the reaction to proceed in high yields. Additionally, the first examples of domino carbohalogenation reactions have been demonstrated… (More)
DOI: 10.1021/ja206099t

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