Palladium-catalyzed Suzuki-Miyaura reaction involving a secondary sp3 carbon: studies of stereochemistry and scope of the reaction.

@article{Rodrguez2007PalladiumcatalyzedSR,
  title={Palladium-catalyzed Suzuki-Miyaura reaction involving a secondary sp3 carbon: studies of stereochemistry and scope of the reaction.},
  author={Nuria Rodr{\'i}guez and Carmen Ram{\'i}rez de Arellano and Gregorio Asensio and Mercedes Medio-Sim{\'o}n},
  journal={Chemistry},
  year={2007},
  volume={13 15},
  pages={4223-9}
}
Palladium-catalyzed C--C bond formation involving secondary sp3-hybridized carbon is described. These reactions occur with secondary 1-bromoethyl arylsulfoxides and different arylboronic acids, to produce the corresponding arylated sulfoxides in moderate to high yields and with complete stereospecificity. Despite the presence of beta hydrogens in the… CONTINUE READING