Palladium- and nickel-catalyzed direct alkylation of azoles with unactivated alkyl bromides and chlorides.

Abstract

Metal-mediated direct C C bond-forming reactions involving C H bond cleavage are commonly of great interest in modern organic chemistry, because of their potential for providing an alternative to the conventional cross-coupling strategy with a stoichiometric amount of organometallic reagents and transformation of ubiquitous C H bonds into diverse functions… (More)
DOI: 10.1002/chem.201001631

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