Pairwise Assembly of Organopalladium(II) Units with Cyanurato(3−) and Trithiocyanurato(3−) Ligands: Formation of Chiral Pd12, Pd10, and Pd9 Cage-Molecules

Abstract

The o-palladated, chloro-bridged dimers [Pd{2-phenylpyridine(-H)}-μ-Cl]2 and [Pd{N,N-dimethylbenzylamine(-H)}-μ-Cl]2 react with cyanuric acid in the presence of base to afford closed, chiral cage-molecules in which 12 organo-Pd(II) centers, located in pairs at the vertices of an octahedron, are linked by four tetrahedrally arranged cyanurato(3-) ligands… (More)
DOI: 10.1021/ic401253q

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