• Chemistry
  • Published 1998

PET-OXIDATIVE REACTIONS OF SILOXY-CYCLOPROPANES

@inproceedings{Rinderhagen1998PETOXIDATIVERO,
  title={PET-OXIDATIVE REACTIONS OF SILOXY-CYCLOPROPANES},
  author={Heiko Rinderhagen and Jochen Mattay},
  year={1998}
}
The oxidative reaction of 1-trimethysiloxy-cyclopropanes has been investigated under PET conditions. The mechanism could be partially elucidated concerning the first reaction steps. The equilibrium of the mutual rearranging exo- and endo- radicals is determined by ring strain and radical-stability.