Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 3.(1) Efficient Oxidation of Buckminsterfullerene C(60) with Methyl(trifluoromethyl)dioxirane.


By employing methyl(trifluoromethyl)dioxirane (1b), the stepwise oxyfunctionalization of C(60) can be carried out with high conversions (>90%) under mild conditions (0 degrees C); the products have been compared with those produced by the oxidation of C(60) with m-chloroperoxybenzoic acid. Along with the previously characterized oxide C(60)O, a wider set of… (More)


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