Oxidation state of uranium in A6Cu12U2S15 (A = K, Rb, Cs) compounds.

@article{Malliakas2012OxidationSO,
  title={Oxidation state of uranium in A6Cu12U2S15 (A = K, Rb, Cs) compounds.},
  author={C. Malliakas and Jiyong Yao and Daniel M. Wells and G. Jin and S. Skanthakumar and E. Choi and M. Balasubramanian and L. Soderholm and D. Ellis and M. Kanatzidis and J. Ibers},
  journal={Inorganic chemistry},
  year={2012},
  volume={51 11},
  pages={
          6153-63
        }
}
Black single crystals of A(6)Cu(12)U(2)S(15) (A = K, Rb, Cs) have been synthesized by the reactive flux method. These isostructural compounds crystallize in the cubic space group Ia ̅3d at room temperature. The structure comprises a three-dimensional framework built from US(6) octahedra and CuS(3) trigonal planar units with A cations residing in the cavities. There are no S-S bonds in the structure. To elucidate the oxidation state of U in these compounds, various physical property measurements… Expand
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