Oxidation of phenols, anilines, and benzenethiols by fungal laccases: correlation between activity and redox potentials as well as halide inhibition.

@article{Xu1996OxidationOP,
  title={Oxidation of phenols, anilines, and benzenethiols by fungal laccases: correlation between activity and redox potentials as well as halide inhibition.},
  author={Feng Xu},
  journal={Biochemistry},
  year={1996},
  volume={35 23},
  pages={7608-14}
}
  • Feng Xu
  • Published 1996 in Biochemistry
A comparative study has been performed with several fungal laccases for the oxidation of a series of phenols, anilines, and benzenethiols and for the inhibition by halides. The observed K(m) and kcat were correlated to the structure of substrate. The change in log (kcat/K(m)) was found to be proportional to the one-electron redox potential difference between laccase's type 1 copper site and substrate. This correlation indicated that the first electron transfer from substrate to laccase was… CONTINUE READING
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