Oxidation of organic compounds by hydrogen peroxide using polymer-anchored azo-metal catalysts

@article{Islam2012OxidationOO,
  title={Oxidation of organic compounds by hydrogen peroxide using polymer-anchored azo-metal catalysts},
  author={Sk. Manirul Islam and Sunirmal Paul and Manir Mobarok and Anupam Singha Roy and Paramita Mondal},
  journal={Transition Metal Chemistry},
  year={2012},
  volume={38},
  pages={7-14}
}
Polymer-anchored azo complexes of Cu(II) and Ni(II) were synthesized by the reaction of chloromethylated polystyrene, 3-aminophenol, and 1-nitroso-2-naphthol with the metal chlorides. The catalytic activities of these complexes were studied in the oxidation of various organic substrates including alkenes, alcohols, alkanes, and sulfides with 30 % aqueous hydrogen peroxide. The structures of both catalysts have been investigated by physiochemical methods. Both catalysts proved to be very stable… CONTINUE READING

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