Oxidation of n-Propylamine and n-Butylamine by Chloramine-B and Chloramine-T in Basic Medium: A Kinetic Study

@article{Veeraiah2010OxidationON,
  title={Oxidation of n-Propylamine and n-Butylamine by Chloramine-B and Chloramine-T in Basic Medium: A Kinetic Study},
  author={M. K. Veeraiah and A. S. Ananda Murthy and Netkal M. Made Gowda},
  journal={Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry},
  year={2010},
  volume={40},
  pages={225 - 230}
}
  • M. Veeraiah, A. Murthy, N. Gowda
  • Published 10 May 2010
  • Chemistry
  • Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
The oxidation of aliphatic primary amines, n-propylamine (PA) and -butylamine (BA), by chloramine-B (CAB) and chloramine-T (CAT) in aqueous alkaline medium has been kinetically studied at 318 K. The reaction follows the experimental rate law: rate k′ [oxidant] [amine] 0 [OH − ] x , where oxidant is CAT or CAB and x is fractional. Additions of chloride ions, the reduction product, sulfonamide, and sodium perchlorate, which is used for changing the ionic strength of the solvent medium, have no… 
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6 Citations

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References

SHOWING 1-10 OF 12 REFERENCES
Oxidation of some primary amines by bromamine‐B in alkaline medium: A kinetic and mechanistic study
The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by sodium N-bromobenzenesulfonamide or bromamine-B (BAB) in sodium hydroxide medium has been…
Kinetic and mechanistic studies of some aliphatic amines' oxidation by sodium N-bromo-p-toluenesulfonamide in hydrochloric acid medium
Oxidations of n-propyl, n-butyl, isobutyl, and isoamyl amines by bromamine-T (BAT) in HCl medium have been kinetically studied at 30°C. The reaction rate shows a first-order dependence on BAT, a…
Chloraminometric reactions: kinetics and mechanisms of oxidations of amino-acids by sodium N-chlorotoluene-p-sulphonamide in acid and alkaline media
TLDR
The rate constants predicted by the derived rate laws, as the concentrations of substrate and Cl– ion change, are in excellent agreement with the observed rate constants thus further verifying the rate laws and hence the proposed mechanisms.
The interaction of N-bromo-N-sodiobenzenesulphonamide (bromamine B) with p-nitrophenoxide ion
By using the interaction with p-nitrophenol as a mechanistic probe it has been established that solutions of N-bromo-N-sodiobenzenesulphonamide (bromamine B) in dilute alkali contain two reactive…
Oxidation of aliphatic amines by aqueous chlorine
The Derivation of a General Kinetic Equation for Reaction Between Ions and Dipolar Molecules
An equation has been derived for the reaction rate constant in the case of ion‐dipole reactions. Section II contains the extension of Debye‐Huckel's theory of ionic atmospheres to the case of dipoles…
Titrimetric analysis with chloramine-T—IThe status of chloramine-T as a titrimetric reagent
Experiments in organic chemistry
simple experiments Organic Chemistry Science Forums EXPERIMENTS IN ORGANIC CHEMISTRY From Microscale to Macroseale Jonathan S. Nimitz University of New Mexico WM PRENTICE HALL, Englewood Cliffs, New…
Chloramine T and related N-halogeno-N-metallo reagents
Kinetics and Mechanism of Iridium(III) Catalyzed Oxidation of Aliphatic Amines by N‐Bromosuccinimide.
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