Oxidation of n-Propylamine and n-Butylamine by Chloramine-B and Chloramine-T in Basic Medium: A Kinetic Study

  title={Oxidation of n-Propylamine and n-Butylamine by Chloramine-B and Chloramine-T in Basic Medium: A Kinetic Study},
  author={M. K. Veeraiah and A. S. Ananda Murthy and Netkal M. Made Gowda},
  journal={Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry},
  pages={225 - 230}
  • M. Veeraiah, A. Murthy, N. Gowda
  • Published 10 May 2010
  • Chemistry
  • Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
The oxidation of aliphatic primary amines, n-propylamine (PA) and -butylamine (BA), by chloramine-B (CAB) and chloramine-T (CAT) in aqueous alkaline medium has been kinetically studied at 318 K. The reaction follows the experimental rate law: rate k′ [oxidant] [amine] 0 [OH − ] x , where oxidant is CAT or CAB and x is fractional. Additions of chloride ions, the reduction product, sulfonamide, and sodium perchlorate, which is used for changing the ionic strength of the solvent medium, have no… 
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