Oxidation of dimethylsulphoxide by sodium m-bromobenzene- sulphonamide: A kinetic and mechanistic study
@article{Mahadevappa1984OxidationOD, title={Oxidation of dimethylsulphoxide by sodium m-bromobenzene- sulphonamide: A kinetic and mechanistic study}, author={Dandinasivara S. Mahadevappa and Sannaiah Ananda and A. S. Ananda Murthy and Kanchugarakoppal S. Rangappa}, journal={Tetrahedron}, year={1984}, volume={40}, pages={1673-1682} }
28 Citations
Oxidation of substituted ethanols by sodium N-bromobenzenesulphonamide: A kinetic study
- Chemistry
- 1989
The kinetics of the oxidation of seven substituted ethanols by sodium N-bromobenzenesulphonamide or bromamine-B (BAB) in the presence of HCl was studied at 45 °C. The rate shows a first-order…
Mechanistic investigation of oxidation of paracetamol by sodium N-chlorobenzenesulphonamide in acid medium
- ChemistryProceedings / Indian Academy of Sciences
- 1999
Oxidation of paracetamol (PAM) by sodium N-chlorobenzenesulphonamide (chloramine-B or CAB) in HClO4 medium at 30°C was studied. The rate is first order in [CAB]0 and fractional order each in [PAM]0…
Kinetics and mechanism of oxidation of 2-hydroxyacetanilide by chloramine-T in HCL medium.
- Chemistry
- 2013
The oxidation kinetics of 2-Hydroxyacetanilide (HA) by sodium N-chloro p-toluenesulfonamide (CAT) in hydrochloric acid medium has been studied at 303K. The reaction stoichiometry was determined and…
Oxidation of substituted phenethyl alcohols by sodium N-chlorobenzenesulphonamide: A kinetic study
- Chemistry
- 1996
The kinetics of the oxidation of sixp-substituted phenethyl alcohols (PEA, R=−H, −Cl, −Br, −CH3, −OCH3, and -NO2) by sodium-N-chloro-p-toluene sulfonamide (chloramine-T,CAT) in the presence of HCl…
Kinetics of oxidation of aliphatic ketones with bromamine-T in acid medium.
- Chemistry
- 1988
The kinetics of oxidation of 2-propanone, 2-butanone, 2-pentanone, 3-pentanone, and 4-methyl-2-pentanone by sodium salt of N-bromo-p-toluenesulfonamide or bromamine-T (BAT) in presence of HClO4 was…
Kinetics and mechanism of oxidation of dimethyl sulphoxide by sodium bromate-sodium bisulphite reagent in aqueous medium
- Chemistry
- 2002
Rates of oxidation of dimethyl sulphoxide (DMSO) by HOBr producedin situ from sodium bromate-sodium bisulphite reagent have been studied iodometrically in aqueous medium. The order in [DMSO] is one…
Mechanistic investigations of the oxidation of phenethyl alcohols by sodium-N-bromo-benzenesulphonamide in acid medium
- Chemistry
- 1996
The kinetics of oxidation of six substituted phenethyl alcohols (X-C6H4-CH2-CH2-OH where X=-H, -Cl, -Br, -CH3, -OCH3 and -NO2) by sodium-N-bromo-benzenesulphonamide or bromamine-B(BAB) in the…
Oxidation of substituted phenethyl alcohols by sodium-N-chloro-p-toluene sulfonamide: A kinetic study
- Chemistry
- 1996
SummaryThe kinetics of the oxidation of sixp-substituted phenethyl alcohols (PEA, R=−H, −Cl, −Br, −CH3, −OCH3, and -NO2) by sodium-N-chloro-p-toluene sulfonamide (chloramine-T,CAT) in the presence of…
References
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Kinetics and mechanism of oxidation of dimethyl sulfoxide by chloramine‐T in aqueous solution
- Chemistry
- 1979
The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine-T (CAT) is studied in HClO4 and NaOH media with OsO4 as a catalyst in the latter medium. In acid medium, the rate law is -d…