Oxidation of Olefins with Benzeneseleninic Anhydride in the Presence of TMSOTf.


A new oxidizing system for olefins, consisting of benzeneseleninic anhydride and trimethylsilyl triflate, was studied. The highly reactive benzeneseleninyl cation is presumably formed under these conditions. It has been shown that different products are formed with this species depending on the specific structure of olefin. The 1,1-disubstituted olefins… (More)
DOI: 10.1021/acs.joc.5b00410


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