Overtone-induced dissociation and isomerization dynamics of the hydroxymethyl radical (CH2OH and CD2OH). II. Velocity map imaging studies.


The dissociation of the hydroxymethyl radical, CH(2)OH, and its isotopolog, CD(2)OH, following excitation in the 4ν(1) region (OH stretch overtone, near 13,600 cm(-1)) was studied using sliced velocity map imaging. A new vibrational band near 13,660 cm(-1) arising from interaction with the antisymmetric CH stretch was discovered for CH(2)OH. In CD(2)OH… (More)
DOI: 10.1063/1.3685899


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