Over-limiting currents and deionization "shocks" in current-induced polarization: local-equilibrium analysis.

@article{Yaroshchuk2012OverlimitingCA,
  title={Over-limiting currents and deionization "shocks" in current-induced polarization: local-equilibrium analysis.},
  author={Andriy Yaroshchuk},
  journal={Advances in colloid and interface science},
  year={2012},
  volume={183-184},
  pages={68-81}
}
The problem is considered theoretically of dynamics of current-induced concentration polarization of interfaces between ideally perm-selective and non-ideally perm-selective ("leaky") ion-exchange media in binary electrolyte solutions under galvanostatic conditions and at negligible volume flow. In contrast to the previous studies, the analysis is systematically carried out in terms of local thermodynamic equilibrium in the approximation of local electric neutrality in virtual solution. For… CONTINUE READING

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